Cardinals of the Catholic Church have failed to elect a new pope on their first day in the Vatican conclave.
The 115 cardinal-electors will vote four times daily until two-thirds can agree on a single candidate.
The election was prompted by the surprise abdication of Benedict XVI. There is no clear frontrunner to take over from him as head of the Church.
The vote was the first held by the cardinals since they entered the conclave on Tuesday afternoon, and was not expected to produce a positive result.
Crowds who had braved rain and storms to watch
the start of the conclave on big screens in St Peter's Square cheered
as the black smoke appeared.
White smoke from the chimney will indicate that a new pope has been chosen.
Pope Benedict's resignation and the recent damage to the Church's reputation make the choice of the cardinal-electors especially hard to predict, the BBC's James Robbins in Rome says.
The 85-year-old Benedict stepped down last month, saying he was no longer strong enough to lead the Church, which is beset by problems ranging from a worldwide scandal over child sex abuse to allegations of corruption at the Vatican Bank.
Isolation
At 16:30 local time (15:30 GMT) on Tuesday, 115 cardinal-electors - all under 80, as those over 80 are excluded - entered the Sistine Chapel, chanting the traditional Litany of the Saints.
Each man in turn stepped up and placed his hands on the Gospel to swear an oath in Latin.
Afterwards Msgr Guido Marini, papal master of ceremonies, called out the words "Extra omnes" - "Everybody out" - and the chapel doors were locked to outsiders.
Jamming devices in the Sistine Chapel should
block all electronic communication and anyone tweeting would in any case
risk being excommunicated.
In his homily, the Dean of the College of Cardinals, Cardinal Angelo Sodano, praised the "brilliant pontificate" of Pope Benedict and implored God to grant another "Good Shepherd" to lead the church.
Benedict - now known as Pope emeritus - resigned on 28 February after eight years in office, citing ill health. He was the first Pope in six centuries to do so.
As Cardinal Joseph Ratzinger in 2005, he was the marked favourite ahead of the conclave and was elected pope after just four rounds of voting.
The vote for his successor is expected to take much longer.
After 10 general congregations open to all cardinals, regardless of age - at which 160 cardinals spoke of the issues facing the Church and the qualities needed by its next leader - no clear frontrunner has emerged.
